I was not a fan of the 1960s television series Get Smart, but I occasionally watched an episode because I admired the look and style of Agent 99, as played by Barbara Feldon.
I liked the 2008 Get Smart film more than the old television series because I admired the look and style of Agent 99, as played by Anne Hathaway, even more than Barbara Feldon's take on Agent 99.
Makeup artist Napoleon Perdis wrote a piece in The Huffiington Post describing how to achieve the look of Anne Hathaway's Agent 99, as well as some other film femme fatales, most notably Angelina Jolie in the new film Salt.
You can read his informative article here.